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Advanced Level Science

Advanced Level Science

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4 months ago

CAMEROON GCE ADVANCED LEVEL CHEMISTRY – Q&A NOTES (COMPREHENSIVE)

For: ClickUP Learning Platform
Format: Q&A for each syllabus topic
Level: Advanced Level (Sciences)

1. ATOMIC STRUCTURE & PERIODICITY

Q1: What is meant by the term “atomic orbital”?

An atomic orbital is a region around the nucleus where there is a high probability of finding an electron. Each orbital has a specific shape and orientation (s, p, d, f).

Q2: State the three quantum numbers and what each represents.

  • n (principal quantum number): Energy level and size of orbital

  • l (azimuthal quantum number): Shape of orbital

  • mₗ (magnetic quantum number): Orientation of orbital

Q3: Why do elements in the same group have similar chemical properties?

They have the same number of valence electrons, resulting in similar bonding behaviour.

Q4: Explain why ionization energy increases across a period.

Nuclear charge increases while shielding remains relatively constant; electrons are held more tightly, requiring more energy to remove.

Q5: Why does atomic radius increase down a group?

Additional energy levels are added, increasing the size of the atom despite increasing nuclear charge.

2. CHEMICAL BONDING

Q1: What is a covalent bond?

A covalent bond is formed when two atoms share one or more pairs of electrons.

Q2: Why are ionic compounds usually soluble in water?

Water molecules are polar and can stabilize ions by hydration, breaking the ionic lattice.

Q3: What is hydrogen bonding? Give examples.

A strong dipole-dipole attraction between H and highly electronegative atoms (N, O, F)
Examples: Water, HF, ammonia.

Q4: Why does diamond have a high melting point?

It has a giant covalent structure where each carbon is covalently bonded to four others, making the structure extremely strong.

Q5: Explain metallic bonding.

Positively charged metal ions are surrounded by a sea of delocalized electrons, giving metals conductivity and malleability.

3. STOICHIOMETRY & CALCULATIONS

Q1: What is the mole?

The amount of substance containing 6.02 × 10²³ particles (Avogadro’s number).

Q2: How do you calculate empirical formula?

Convert masses to moles → divide by smallest mole value → multiply to whole numbers.

Q3: Define percentage purity.

Percentage purity = (mass of pure substance ÷ total mass of impure sample) × 100.

Q4: What is molar volume at RTP?

At room temperature and pressure, 1 mole = 24 dm³ of gas.

4. STATES OF MATTER & KINETIC THEORY

Q1: What is Boyle’s Law?

For a fixed mass of gas at constant temperature:
P ∝ 1/V or PV = constant

Q2: Why do real gases deviate from ideal behaviour?

Because real molecules have intermolecular forces and non-zero volumes.

Q3: What happens at the boiling point on the energy level?

Energy is used to break intermolecular forces, not increase temperature.

5. THERMODYNAMICS

Q1: Define enthalpy change of formation.

Heat change when 1 mole of a compound is formed from its elements in their standard states.

Q2: What is Hess’s Law?

The total enthalpy change of a reaction is the same regardless of the route taken.

Q3: Why are bond-breaking processes endothermic?

Energy is required to overcome attraction between particles.

6. CHEMICAL KINETICS

Q1: What is activation energy?

Minimum energy needed for reacting molecules to form products.

Q2: How does temperature affect reaction rate?

Increases frequency and energy of collisions → more particles exceed activation energy.

Q3: Why do catalysts increase reaction rate?

They provide an alternative pathway with lower activation energy.

7. CHEMICAL EQUILIBRIUM

Q1: State Le Chatelier’s Principle.

A system at equilibrium adjusts to oppose any applied change.

Q2: What happens to equilibrium when pressure is increased?

It shifts towards the side with fewer moles of gas.

Q3: What is the equilibrium constant Kc?

Kc = (product concentrations) / (reactant concentrations), each raised to stoichiometric powers.

8. ACIDS, BASES & SALTS

Q1: What is a Bronsted-Lowry acid?

A proton donor.

Q2: Why is water amphoteric?

It can act as both a proton donor and acceptor.

Q3: What is a buffer solution?

A solution that resists changes in pH when small amounts of acid or base are added.

Q4: What is hydrolysis of salts?

Reaction of salt ions with water to form acidic or basic solutions.

9. REDOX REACTIONS & ELECTROCHEMISTRY

Q1: Define oxidation in terms of electrons.

Loss of electrons.

Q2: What is a standard electrode potential?

Voltage developed when a metal is in contact with 1M of its ions under standard conditions.

Q3: Why do reactive metals have highly negative electrode potentials?

They easily lose electrons to form positive ions.

Q4: What is electrolysis?

Decomposition of an electrolyte using electric current.

10. ORGANIC CHEMISTRY

Q1: What is a homologous series?

A family of organic compounds with similar chemical properties and the same functional group.

**Q2: State the general formula of:

  • Alkanes • Alkenes • Alkynes**
  • Alkanes: CₙH₂ₙ₊₂

  • Alkenes: CₙH₂ₙ

  • Alkynes: CₙH₂ₙ₋₂

Q3: What is isomerism?

Compounds with the same molecular formula but different structural arrangements.

Q4: Why do alcohols have higher boiling points than alkanes?

Presence of hydrogen bonding.

Q5: What are nucleophiles and electrophiles?

  • Nucleophiles: Electron-pair donors

  • Electrophiles: Electron-pair acceptors

11. ANALYTICAL CHEMISTRY

Q1: What is chromatography?

A separation technique based on different rates of movement through a medium.

Q2: What is the Rf value?

Distance travelled by substance ÷ distance travelled by solvent.

Q3: Why is titration used?

For accurate determination of unknown concentrations.

Q4: How does a calorimeter work?

It measures heat changes during chemical reactions.

12. TRANSITION METALS

Q1: Why do transition metals form coloured ions?

Due to d–d electron transitions when light is absorbed.

Q2: Why do transition metals act as catalysts?

They can change oxidation states and provide alternative reaction pathways.

Q3: What is a complex ion?

A central metal ion surrounded by ligands bonded through coordinate bonds.

13. NUCLEAR CHEMISTRY

Q1: What is radioactive decay?

Spontaneous emission of radiation from unstable nuclei.

Q2: State the three types of radiation.

Alpha, Beta, Gamma.

Q3: What is half-life?

Time taken for half of the radioactive nuclei to decay.

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